Darwin 8.0.1 (corresponding to Mac OS X 10.4) seems to be the latest available full installer image, at least, until the PureDarwin project produces a new one.
Latests gcc_42 package (newer packages are named gcc). GCC 4.2.1. Requires patched system include files, which can be done when upgrading xnu and Libc (see above).
Source package: gcc_42-5577.tar.gz (update to version listed under “Mac OS X 10.5.8”)